Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen
Identifieur interne : 000D50 ( Main/Exploration ); précédent : 000D49; suivant : 000D51Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen
Auteurs : Joachim Ballmann ; Alyssa Yeo ; Brian O. Patrick ; Michael D. Fryzuk [Canada]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2011-01-10.
English descriptors
- Teeft :
- Angew, Bond cleavage, Bond formations, Bond lengths, Carbon atoms, Carbon dioxide, Carbon disulfide, Chem, Dalton trans, Dinitrogen, Fryzuk, Latter moiety, Ligand, Ligand rings, Mackay, Molecular structure, Phenyl isothiocyanate, Room temperature, Silyl, Silyl methyl groups, Single crystals, Single product, Triple bonds, Verlag gmbh, Weinheim angew.
Abstract
Some dinitrogen on the side: 1,2‐cumulenes, such as carbodiimides, carbon disulfide, and isothiocyanates, react with the side‐on end‐on N2 tantalum complex through a [2+2] cycloaddition pathway to result in the formation of new carbon–nitrogen bonds.
Url:
DOI: 10.1002/anie.201005704
Affiliations:
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Le document en format XML
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